%0 Journal Article %T Radical allylation with a-branched allyl sulfones %+ Laboratoire de synthèse organique (DCSO) %A Charrier, Nicolas %A Zard, Samir, Z. %< avec comité de lecture %@ 1433-7851 %J Angewandte Chemie International Edition %I Wiley-VCH Verlag %V 47 %N 49 %P 9443-9446 %8 2008 %D 2008 %R 10.1002/anie.200804298 %Z Chemical Sciences/Organic chemistryJournal articles %X (Chemical Equation Presented) Branching out with sulfones: The use of allyl isopropyl sulfones solves the problem of premature isomerization and allows the radical addition of xanthates to a-branched allyl sulfones (see scheme; DCE=1,2-dichloroethane, TMS=trimethylsilyl). Highly functionalized structures can thus be rapidly assembled under mild reaction conditions by using cheap and readily available substrates and reagents. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. %G English %L hal-00951276 %U https://polytechnique.hal.science/hal-00951276 %~ X %~ CNRS %~ X-DCSO %~ X-DEP %~ X-DEP-CHIM %~ INC-CNRS %~ TEST2-HALCNRS