%0 Conference Paper %F Oral %T Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship %+ Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA) %+ Centre de Recherches et Technologies d'Aubervilliers %+ Laboratoire de synthèse organique (DCSO) %+ Laboratoire de Chimie des polymères organiques (LCPO) %A Destarac, Mathias %A Ruchmann, Juliette %A Vila, Xavier %A Zard, Samir, Z. %A van Gramberen, E. %A Taton, Daniel %< avec comité de lecture %B 5th Controlled/living Radical Polymerization Symposium, The 236th ACS National Meeting %C Philadelphia, United States %P POLY 323 %8 2008-08-17 %D 2008Conference papers %X A new series of xanthate MADIX agents bearing a-amido trifluoromethyl leaving R groups and exhibiting a good ability for fragmentation is kinetically investigated. Quantitative measurements of both Ctr for xanthates and Cex faithfully supported the experimental observations for Mn and PDIs. %G English %L hal-00965844 %U https://polytechnique.hal.science/hal-00965844 %~ X %~ UNIV-TLSE3 %~ CNRS %~ UNIV-BORDEAUX %~ X-DCSO %~ X-DEP %~ X-DEP-CHIM %~ INC-CNRS %~ LCPO %~ TOULOUSE-INP %~ UNIV-UT3 %~ UT3-INP %~ UT3-TOULOUSEINP %~ TEST2-HALCNRS %~ LHFA