Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship
Abstract
A new series of xanthate MADIX agents bearing a-amido trifluoromethyl leaving R groups and exhibiting a good ability for fragmentation is kinetically investigated. Quantitative measurements of both Ctr for xanthates and Cex faithfully supported the experimental observations for Mn and PDIs.