Enyne versus diene RCM in the synthesis of cyclopentene derivatives toward the A ring of FR182877 - École polytechnique Access content directly
Journal Articles Journal of Organic Chemistry Year : 2004

Enyne versus diene RCM in the synthesis of cyclopentene derivatives toward the A ring of FR182877

Abstract

The A ring of FR182877, exemplified by ent-4-b,c, has been synthesized, involving an enyne RCM as the key step. A systematic comparison of enyne vs diene RCM for the formation of cyclopentene derivatives showed that the latter metathesis proceeds much more easily even for this ring size.

Dates and versions

hal-00954815 , version 1 (24-03-2014)

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Jacques-Alexis Funel, Joëlle Prunet. Enyne versus diene RCM in the synthesis of cyclopentene derivatives toward the A ring of FR182877. Journal of Organic Chemistry, 2004, 69 (13), pp.4555-4558. ⟨10.1021/jo049557d⟩. ⟨hal-00954815⟩
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