New radical homoallylation reactions - École polytechnique Access content directly
Journal Articles SYNLETT Year : 2003

New radical homoallylation reactions

Abstract

Xanthate addition to 3-aryl-4-methanesulfonylbutene and structurally related derivatives triggers a cascade involving aryl migration and elimination of a sulfonyl radical, the result being an overall homoallylation of the initial radical. Other slow migrating groups such as an ester can replace the aryl group.
No file

Dates and versions

hal-00954831 , version 1 (21-03-2014)

Identifiers

Cite

Gilles Ouvry, Samir Z. Zard. New radical homoallylation reactions. SYNLETT, 2003, 11, pp.1627-1630. ⟨10.1055/s-2003-41011⟩. ⟨hal-00954831⟩
117 View
0 Download

Altmetric

Share

Gmail Facebook X LinkedIn More