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Journal Articles Organic Letters Year : 2003

ß-nitro xanthates as olefin precursors

Abstract

(Matrix presented) Potassium O-ethyl xanthate readily adds to a,ß-unsaturated nitro compounds to give stable ß-nitro xanthates, which undergo tin-free elimination to form olefins in good yield and good E selectivity upon simple heating with lauroyl peroxide in refluxing 1,2-dichloroethane.
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hal-00954834 , version 1 (18-03-2014)

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Gilles Ouvry, Béatrice Quiclet-Sire, Samir Z. Zard. ß-nitro xanthates as olefin precursors. Organic Letters, 2003, 5 (16), pp.2907-2909. ⟨10.1021/ol035027c⟩. ⟨hal-00954834⟩
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