The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst: Olefin metathesis versus olefin isomerization - École polytechnique Access content directly
Journal Articles Journal of Organometallic Chemistry Year : 2002

The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst: Olefin metathesis versus olefin isomerization

Abstract

While investigating RCM of substrates requiring elevated temperatures and extended reaction times, significant isomerization of one of the double bonds in the starting diene was observed with the recently developed [RuIMes] catalyst. This isomerization appeared as an important drawback of the catalyst, but a judicious selection of solvent and additive can completely eliminate this side reaction. © 2002 Elsevier Science B.V. All rights reserved.

Dates and versions

hal-00954863 , version 1 (17-03-2014)

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Damien Bourgeois, A. Pancrazi, S.P. Nolan, Joëlle Prunet. The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst: Olefin metathesis versus olefin isomerization. Journal of Organometallic Chemistry, 2002, 643-644 (-), pp.247-252. ⟨10.1016/s0022-328x(01)01269-4⟩. ⟨hal-00954863⟩
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