Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents - École polytechnique Access content directly
Journal Articles Macromolecular Rapid Communications Year : 2000

Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents

Mathias Destarac
  • Function : Author
  • PersonId : 855806
D. Charmot
  • Function : Author
Samir Z. Zard
  • Function : Author
  • PersonId : 953506

Abstract

Control of the radical polymerization of acrylates, styrene and vinyl acetate has been achieved by using novel dithiocarbamates as reversible addition-fragmentation chain transfer agents. The key parameter for the control with N,N-disubstituted (A) or cyclic (B) dithiocarbamates was found to be the conjugation of the lone pair of electrons of the nitrogen atom with carbonyl or aromatic groups. © WILEY-VCH Verlag GmbH 2000.

Dates and versions

hal-00954901 , version 1 (11-03-2014)

Identifiers

Cite

Mathias Destarac, D. Charmot, X. Franck, Samir Z. Zard. Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents. Macromolecular Rapid Communications, 2000, 21 (15), pp.1035-1039. ⟨10.1002/1521-3927(20001001)21:15<1035::AID-MARC1035>3.0.CO;2-5⟩. ⟨hal-00954901⟩
164 View
0 Download

Altmetric

Share

Gmail Facebook X LinkedIn More