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Journal Articles Organic Letters Year : 2003

beta-Nitro xanthates as olefin precursors.


[reaction: see text] Potassium O-ethyl xanthate readily adds to alpha,beta-unsaturated nitro compounds to give stable beta-nitro xanthates, which undergo tin-free elimination to form olefins in good yield and good E selectivity upon simple heating with lauroyl peroxide in refluxing 1,2-dichloroethane.
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hal-00969322 , version 1 (02-04-2014)



Gilles Ouvry, Béatrice Quiclet-Sire, Samir Z. Zard. beta-Nitro xanthates as olefin precursors.. Organic Letters, 2003, 5 (16), pp.2907-2909. ⟨10.1021/ol035027c⟩. ⟨hal-00969322⟩
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