Tin-free radical sequences under acidic conditions. Convergent access to azole-containing structures. - École polytechnique Access content directly
Journal Articles Organic Letters Year : 2002

Tin-free radical sequences under acidic conditions. Convergent access to azole-containing structures.

Abstract

[reaction: see text] Various xanthates add efficiently to olefins bearing [1,2,4]triazole, imidazole, or benzimidazole moieties in the presence of camphorsulfonic acid via a radical chain reaction initiated by a small amount of lauroyl peroxide. The adducts may be transformed to more complex molecules by implementing a further radical cyclization.
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hal-00969328 , version 1 (02-04-2014)

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Fabien Gagosz, Samir Z. Zard. Tin-free radical sequences under acidic conditions. Convergent access to azole-containing structures.. Organic Letters, 2002, 4 (24), pp.4345-4348. ⟨10.1021/ol0270024⟩. ⟨hal-00969328⟩
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