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Journal Articles Organic Letters Year : 2014

Carbon Radical Attack on a Pyrimidine Nitrogen. An Unusual Entry into Polycyclic Aminopyrimidones

Abstract

Unprecedented examples of a synthetically useful radical ring closure onto a pyrimidine nitrogen leading to novel, highly functionalized bi- and tricyclic pyrimidone structures are reported. An unexpected hydrogen atom translocation prior to the cyclization step was observed in some cases.
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hal-01017929 , version 1 (03-07-2014)

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Ling Qin, Zhibo Liu, Samir Z. Zard. Carbon Radical Attack on a Pyrimidine Nitrogen. An Unusual Entry into Polycyclic Aminopyrimidones. Organic Letters, 2014, 16 (11), pp.2966-2969. ⟨10.1021/ol501104h⟩. ⟨hal-01017929⟩
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