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Journal Articles Synthesis: Journal of Synthetic Organic Chemistry Year : 2014

Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange

Abstract

Irreversible acid-nitrile exchange reactions using both glutaronitrile and (phenylsulfonyl)acetonitrile may be catalyzed by Lewis acids. Whereas a cyclization towards imides displaces the equilibria in the reaction with dinitriles, a decarboxylation step is involved when using the (phenylsulfonyl)acetonitrile.
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hal-01044733 , version 1 (24-07-2014)

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Damien Cartigny, Aurélie dos Santos, Laurent El Kaim, Laurence Grimaud, Roland Jacquot, et al.. Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange. Synthesis: Journal of Synthetic Organic Chemistry, 2014, 46 (13), pp.1802-1806. ⟨10.1055/s-0033-1341227⟩. ⟨hal-01044733⟩
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