Chemoselective Reduction: Xanthates as Traceless Precursors of Polyfunctionalized α,α-Dichloroketones - École polytechnique Access content directly
Journal Articles Organic Letters Year : 2017

Chemoselective Reduction: Xanthates as Traceless Precursors of Polyfunctionalized α,α-Dichloroketones

Samir Z. Zard
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Abstract

The use of BEt3·H2O has allowed the chemoselective reductive dexanthylation in the presence of the very fragile α,α-dichloroketone motif. This has solved a major hurdle in our approach to this important, but hitherto grossly understudied, family of compounds and opened access to a number of very useful synthetic transformations.
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hal-02091721 , version 1 (06-04-2019)

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Lucile Anthore-Dalion, Samir Z. Zard. Chemoselective Reduction: Xanthates as Traceless Precursors of Polyfunctionalized α,α-Dichloroketones. Organic Letters, 2017, 19 (20), pp.5545-5548. ⟨10.1021/acs.orglett.7b02636⟩. ⟨hal-02091721⟩
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